Alkoxy and Phenoxy Bridged Dimeric Copper(II) Complexes with Salicylaldimine Ligands
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چکیده
منابع مشابه
Synthesis, Spectroscopy and Magnetism of Alkoxobridged Dinuclear Copper(II) Complexes with 2 Amino Picolines as the Ligands
The synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (II) compounds are described. All complexes have the general formula [Cu (m-OR)(L)2]2(ClO4)2 · x H2O, in which m-OR = CH3O-, C2H5O- or C3H7O-<e...
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The reaction of CuSO4·5H2O, 4-chloro-pyrazole (4-Cl-pzH) and tri-ethyl-amine (Et3N) in di-methyl-formamide (DMF) produced crystals of di-aqua-hexa-kis-(μ-4-chloro-pyrazolato-κ(2) N:N')bis-(N,N-di-methyl-formamide)di-μ3-hydroxido-bis-(μ4-sulfato-κ(4) O:O':O'':O'')hexa-copper(II) N,N-di-methyl-formamide tetra-solvate dihydrate, [Cu3(OH)(SO4)(C3H2ClN2)3(C3H7NO)(H2O)]2·4C3H7NO·2H2O. The centrosymme...
متن کاملsynthesis, spectroscopy and magnetism of alkoxobridged dinuclear copper(ii) complexes with 2 amino picolines as the ligands
the synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (ii) compounds are described. all complexes have the general formula [cu (m-or)(l)2]2(clo4)2 · x h2o, in which m-or = ch3o-, c2h5o- or c3h7o-, l = 2-amino-4-methylpyridine (abbreviated a4pic) and 2-amino-5-methylpyridine ( abbreviated a5pic). the title compounds all consist of dinuclear...
متن کاملChloride-bridged oxovanadium(V) complexes with alkoxyalkoxide ligands. Synthesis, structure, electrochemistry and reactivities.
A series of mixed alkoxyalkoxo chloro complexes of vanadium(V), [VOCl2(OCH2CH2OR)]2 (R = Me, Et, iPr, Bz), [VOCl2(OCMe2CH2OMe)]2 and [VOCl2(OCH2(cyclo-C4H7O)]2, were synthesised and characterised. The title compounds can be obtained either from VOCl3 and the alkoxyalcohols by HCl elimination or from the corresponding lithium alkoxides and VOCl3 by salt metathesis reaction. X-Ray diffraction stu...
متن کاملDimeric versus polymeric coordination in copper(II) cationic complexes with bis(chelating) oxime and amide ligands.
A series of copper(ii) complexes with earlier reported ligands N,N'-bis(2-hydroxyiminopropionyl)-1,2-diaminoethane (H(2)pen) and 1,3-diaminopropane (H(2)pap) and novel open chain oxime and amide ligands, N,N'-bis(2-hydroxyiminopropionyl)-1,5-diaminopentane (H(2)papt), 1,6-diaminohexane (H(2)pah) and 1,7-diaminoheptane (H(2)pahp), were prepared and characterized by a variety of spectroscopic met...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1973
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.46.1457